Enzymatic biodiesel production kinetics under previously optimized conditions were investigated. Transesterification and production of biodiesel from waste. Transesterification reaction kinetics of jatropha oil for biodiesel production. The most commonly used method of production of biodiesel is transesterification which is a reaction between a lipid and an alcohol in the presence of a catalyst to form esters and glycerol. The parameters affecting biodiesel production process such as alcohol to oil molar ratio, catalyst concentration, the presence of tetrahydrofuran thf as a cosolvent, and the volumetric flow rates of. After twentyfive years of study, the description of the reaction kinetics remains controversial. Kinetics of transesterification of soybean oil springerlink. Enzymatic biodiesel production kinetics using cosolvent and. The fuel can be made easily from either virgin or waste vegetable oil. Kinetics of transesterification processes for biodiesel. Studies on esterification of free fatty acids in biodiesel. The purity of the biodiesel product was examined using gas chromatography to the en14214 fame standard and realtime optical microscopy was used to observe the reaction. Nov 12, 2002 the reaction of rapeseed oil with methanol catalyzed by koh is described by a model consisting of two sequences of consecutive competitive reactions. It is alkali catalyzed reaction which involves waste cooking oil, methanol, and potassium hydroxide.
Pdf transesterification reaction kinetics of jatropha oil. But, relevant work was rarely found in the existing literature, particularly for. Previous studies on biodiesel production processes including esterification and transesterification were conducted in a wellmixed system, in which the hydrodynamic effect on the reaction could not be completely defined. Kinetics data associated with subcritical methanol reactions are essential for biodiesel production plant design. There are conflicting findings as to the order of reaction, and estimates of reaction rate constants vary widely. Modelling and optimisation of biodiesel production from. Therefore, the objective of this research is to provide a better understanding of the reaction kinetics of.
A comparative analysis of biodiesel and diesel emissions. The results obtained in the kinetics study were applied in the operation of a semicontinuous reactor for biodiesel production. Kinetics of used soybean frying oil was reported to follow a. Hielscher ultrasonic reactors improve the transesterification kinetics significantly. The aim of this paper was to investigate the kinetics of the biodiesel reaction in order to find out how best to reach 96. Waste frying oil wfo was used as the raw material, novozym 435 as catalyst, methanol as acyl acceptor and tertbutanol as cosolvent. Kinetics of production of biodiesel by enzymatic methanolysis of vegetable oils using lipase has been investigated. In order to reduce the overall production cost of biodiesel, waste cooking oil feedstock was used. They found that the delay in the formation of methyl ester became less with the increase of impeller speed from 300 to 600 rpm, indicating that the mass transfer control mechanism became. In the initial stages of the reaction, production of me was rapid. A mathematical model taking into account the mechanism of the methanolysis reaction starting from the vegetable oil as substrate, rather than the free fatty acids, has been developed. Both ethyl and methyl biodiesel were refined and combusted. The reactions were carried out with three kinds of fatty acids stearic, palmitic, and lauric with anhydrous. Modeling and simulation of reaction kinetics for biodiesel production.
Complete heterogeneous catalysts were used to promote the transesterification reaction of waste cooking oil wco. Sulfated zirconia is a solid super acid catalyst that widely used in many process due to its strong acid properties 23. Characterization and kinetics of biofuel produced from. The following committee members have found the thesis acceptable in form and content, and that the candidate demonstrated satisfactory knowledge of the subject material. Modeling and simulation of reaction kinetics for biodiesel. Ethanol is the most used because of its low cost, however, greater. After analyzing the prior work on kinetics, this thesis gives support to a kinetic model. Okullo, temu and ntalikwa 221 transesterification reaction kinetics of jatropha oil for biodiesel production a. Biodiesel synthesis via transesterification reaction in. The chemical kinetics of glycerolysis biodiesel magazine. The kinetic of fatty acids esterification with ethanol utilizing niobium oxide catalyst 79.
Production of biodiesel 4 impeller speed and reaction temperature refer to figure 1. Transesterification of soybean oil with methanol was investigated. Monitoring the mechanism and kinetics of a transesterification reaction for the biodiesel production with low field 1h nmr spectroscopy. Biodiesel production is the process of producing the biofuel, biodiesel, through the chemical reactions of transesterification and esterification. It is prepared from waste vegetable oils and animal fats by transesterification process. Transesterification reaction kinetics of jatropha oil for. Biodiesel has emerged as a viable substitute for petroleum diesel.
Biodiesel in chemcad the challenge biodiesel production. These plants use a mixture of animal fats, soy oils or multiple different feedstocks as the reactant. Determination of the kinetics of biodiesel production using. The amount of methanol added is almost double the required amount so the reaction goes to completion. Reaction kinetics of biodiesel production by using low.
Saponification reaction high soap content reduces the amount of catalyst for transesterification causes problems in downstreamcleaning processing. The first sequence expresses the methanolysis of rapeseed oil to methyl esters biodiesel whereas the second sequence describes the always present side reaction. It is wellknown to be an alternative sustainable fuel source to decrease the depletion rate of fossil fuels, due. Figure 1 shows the progress of the transesterification reaction for palm oil in the first 90 min of reaction time. Production of biodiesel from acid oil using sulfuric acid. A logical reaction rate coupling model, which is dependent on the acoustic pressure and flow velocity, is used to evaluate the kinetics of the reaction, which are to be used as a judging factor for the reactor design 2. Astm international originally known as the american society for testing and. The kinetics of transesterification reaction for biodiesel production is one of the topic which several authors have reported due to this data can be used to design, optimize, control and scaled up conditions in the biodiesel production process to industrial scale.
Reaction kinetics of transesterification between palm oil and. Since feedstock costs account for a large percent of the direct biodiesel production costs, use of waste cooking oils or inedible and low cost oils ex. The alcohols used should be of low molecular weight. Although glycerolysis can be run at these lower temperatures, reaction kinetics are vastly improved when run at temperatures at or above 450 f. When you make biodiesel, slow reaction kinetics and poor mass transfer are lowering your biodiesel plant capacity and your biodiesel yield and quality. An analytical comparison of ethanolysis and methanolysis. They found that the delay in the formation of methyl ester became less with the increase of impeller speed from 300 to 600 rpm, indicating that the mass transfer control mechanism became less important with increase in stirring rate. Biodiesel transesterification kinetics monitored by ph. The production of biodiesel from waste vegetable oils through its pretreatment followed by transesterification process in presence of methanol was investigated using a km micromixer reactor. Monitoring the production of glycerol allowed for the study of the reaction kinetics and determination of the rate constants at various temperatures, and therefore the overall activation energy as defined by the arrhenius equation.
Three stepwise and reversible reactions are believed to occur. The most commonly used method of production of biodiesel is transesterification which. Fatsoils to biodiesel reaction the three basic methods of ester production from oilsfats are 1 base catalyzed transesterification, 2 acid catalyzed esterification, and 3 enzymatic catalysis. Production of biodiesel from acid oil using sulfuric acid as. Ganapathi department of biotechnology, bharathidasan university, tiruchirappalli, tamilnadu, india 620 024 corresponding author e mail. Production of biodiesel from cottonseed oil over aminated. After twentyfive years of study, the description of the kinetics of transesterification for biodiesel remains controversial. The kinetic study of transesterification reaction for. They however explained that scaleup from laboratory scale to pilot scale is still a major challenge. May 15, 2014 many biodiesel plants run their processes using steam heating systems, and are limited to operating temperatures of 350 degrees fahrenheit or less. Biodiesel has received most interest because 90% of the total world energy is consumed by the transportation sector 2.
Process standardization and kinetics of ethanol driven. Pdf kinetics of transesterification processes for biodiesel. Pdf on jul 11, 2018, fernando trejozarraga and others published kinetics of transesterification processes for biodiesel production find, read and cite all the research you need on researchgate. A reaction scheme for the biodiesel production, for example, through enzymatic processes, can consider much more reaction steps and thus a higher number of reaction parameters. Reaction kinetics of transesterification between palm oil. Biodiesel, or fatty acid alkyl ester ffae, is made up of methyl or ethyl esters produced from vegetable oil or animal fat.
Both ethyl and methylbiodiesel were refined and combusted. Pdf investigation of the parameters affecting castor oil. The effect of variations in mixing intensity reynolds number3,100 to 12,400 and temperature 30 to 70c on the rate of reaction were studied while the molar ratio of alcohol to triglycerol 6. Kinetics of palm oil transesterification in a batch reactor. The controlling step method was employed to obtain the kinetic equations, and nonlinear multiparametric routine was implemented to estimate the kinetic parameters. Pdf influence of mass transfer and kinetics on biodiesel. The reaction of rapeseed oil with methanol catalyzed by koh is described by a model consisting of two sequences of consecutive competitive reactions. Transesterification, ultrasound, biodiesel, process intensification, numerical modelling.
Reaction kinetic study of biodiesel production from fatty. Kinetics and mechanism of the koh catalyzed methanolysis of. The most cursory look at the literature relating to biodiesel will soon reveal the following relationship for prediction of biodiesel from fats and oils. With 100 lbs of fat and 1620 lbs of alcohol and 1 lb of catalyst, the reaction will produce 100. This involves vegetable or animal fats and oils being reacted with shortchain alcohols typically methanol or ethanol. Systems engineering, has presented a thesis titled, reaction kinetics of biodiesel production by using low quality feedstock,in an oral examination held on august 30, 20. Pdf transesterification reaction kinetics of jatropha. It is wellknown to be an alternative sustainable fuel source to decrease the depletion rate of fossil fuels, due to its similar fuel properties to the diesel fuel. Jul 12, 2010 the kinetic of fatty acids esterification with ethanol utilizing niobium oxide catalyst 79. It note worth mentioning that the low values of apparent reaction rate constants in the present study suggests that the mass transfer limitations are minimal in the present transesterification reaction and confirms that the kinetics of biodiesel production is controlled by the adsorption of methanol onto the active sites of the catalyst. Nov 06, 2016 it is prepared from waste vegetable oils and animal fats by transesterification process. Ntalikwa2 1researcher, department of chemical and mining engineering, university of dar es salaam, p. A common means of production is basecatalyzed transesterification.
The presence of free fatty acids is the controlling parameter of the method process used for biodiesel production. Biodiesel foundation fuels rapid compression machine highpressure ignition thermometry and species c. The kinetics of the esterification and transesterification reaction of an acid oil 10% of initial free fatty acid was studied using ethanol and a homogenous acid catalyst. Enzymatic biodiesel production kinetics using cosolvent.
The operational conditions of each reaction cycle were. Kinetics and mechanism of the koh catalyzed methanolysis. The study focus on the physical and chemical properties of waste cooking oil wco, transesterification and production of biodiesel from wco. Determination of the kinetics of biodiesel production. Biodiesel is defined as long chain monoalkyl esters of vegetable oils and animal fats. Production of biodiesel from waste vegetable oil via km. Investigation of the parameters affecting castor oil transesterification reaction kinetics for biodiesel production. Developing the reaction kinetics for a biodiesel reactor. Sulfated zirconia is a solid super acid catalyst that widely used in many process due to its strong acid. The cost of lipases and the relatively slower reaction rate remain as the major obstacles for enzymatic production of biodiesel as opposed to the conventional chemical processes.
251 1091 415 292 1296 788 284 514 315 1210 1160 360 1242 650 1359 1198 980 944 657 1021 1455 638 605 1127 220 1028 1282 92 247 927 449